Publikationsliste / List of Publications

ORCID (L. Hintermann): orcid.org/0000-0003-2622-8663

 

 

Zeitschriftenartikel, Buchkapitel (Papers, Book-Chapters)

 

2018

 

76. S. Koller, J. Gatzka, K. M. Wong, P. Altmann, A. Pöthig. L. Hintermann,* J. Org. Chem. 2018, 83, 15009–15028. DOI: 10.1021/acs.joc.8b02278

"Stereochemistry of the Menthyl Grignard Reagent: Generation, Composition, Dynamics, and Reactions with Electrophiles"  

 

75. S. Koller, M. Blazejak, L. Hintermann,* Eur. J. Org. Chem. 2018, 1624–1633. DOI: 10.1002/ejoc.201800146

"Catalytic C-Alkylation of Pyrroles with Primary Alcohols: Hans Fischer's Alkali, and a New Spin with Iridium P,N,P-Pincer Complexes"

 

2017

 

74. M. Schreyer, L. Hintermann,* Beilstein J. Org. Chem. 2017, 13, 2332–2339.

"Is the tungsten(IV) complex (NEt4)2[WO(mnt)2] a functional analogue of acetylene hydratase?" (Open Access)

 

73. S. Chatterjee, L. Hintermann, M. Mandal, A. Achari, S. Gupta, P. Jaisankar,* Org. Lett. 2017, 19, 3426–3429.

"Fiaud’s Acid: A Brønsted Acid Catalyst for Enantioselective Friedel–Crafts Alkylation of Indoles with 2-Alkene-1,4-diones"

 

72. L. Hintermann,* K. M. Wong, Eur. J. Org. Chem. 2017, 5527–5536.

"Rearrangement in Stereoretentive Syntheses of Menthyl chloride from Menthol: Insight into Competing Reaction Pathways through Component Quantification Analysis"

 

71. A. Ghose, O. V. Maltsev, N. Humbert, L. Hintermann, Y. Arntz, P. Naumov, Y. Mély, P. Didier,* J. Phys. Chem. B. 2017, 121, 1566–1575.

"Oxyluciferin Derivatives: A Toolbox of Environment-Sensitive Fluorescence Probes for Molecular and Cellular Applications"

 

70. L. Hintermann,* P. J. Altmann, P. Naumov, K. Suzuki, Helv. Chim. Acta 2017100, e1600392.

"Synthesis of Tetraoxygenated Terephthalates via a Dichloroquinone Route: Characterization of Cross-Conjugated Liebermann Betaine Intermediates"

 

69. M. Wiedemann, P. J. Altmann, L. Hintermann,* Synthesis 201749, 2257–2265.

"Mannich N-Indolylmethylation of Amino Acids"

 

2016

 

68. L. Hintermann, ARPYPHOS Ligands for Anti-Markovnikov Alkyne Hydration in e-EROS Encyclopedia of Reagents for Organic Synthesis, John Wiley & Sons Ltd., 2016; DOI: 10.1002/047084289X.rn01961

"ARPYPHOS Ligands for Anti-Markovnikov Alkyne Hydration"

 

67. A. Brunner, L. Hintermann,* Helv. Chim. Acta 2016, 99, 928–943.

"Configurational Assignment of "Cryptochiral" 10-Hydroxystearic Acid Through an Asymmetric Catalytic Synthesis"

 

66. N. Saleh,* A. R. B. Suwaid, A. Alhalabi, A. Z. A. Abuibaid, O. V. Maltsev, L. Hintermann, P. Naumov,* J. Phys. Chem. B 2016, 120, 7671–7680.

“Bioinspired Molecular Lantern: Tuning the Firefly Oxyluciferin Emission with Host–Guest Chemistry”

 

65. A. Brunner, L. Hintermann,* Chem. Eur. J. 2016, 22, 2787–2792.

"A Sequential Homologation of Alkynes and Aldehydes for Chain Elongation with Optional 13C-Labeling"

 

64. A. Bräuer, P. Beck, L. Hintermann,* M. Groll,* Angew. Chem. 2016, 128, 432–436; Angew. Chem. Int. Ed. 2016, 55, 422–426.

"Struktur der Dioxygenase AsqJ: mechanistische Einblicke in die Eintopf-Mehrstufen-Biosynthese eines Chinolonantibiotikums" (Ger.); "Structure of the Dioxygenase AsqJ: Mechanistic Insights into a One-Pot Multistep Quinolone Antibiotic Biosynthesis" (Engl.) 

 

2015

 

63. L. Xiao, A. Pöthig, L. Hintermann,* Monatsh. Chem. 2015, 146, 1529–1539.

"2-Amino-1,3,5-triazine Chemistry: Hydrogen-Bond-Networks, Takemoto Thiourea Catalyst Analogs, and Olfactory Mapping of a Sweet-Smelling Triazine"

 

62. J. Schlüter, M. Blazejak, F. Boeck, L. Hintermann,*  Angew. Chem. 2015, 127, 4086–4089; Angew. Chem. Int. Ed. 2015, 54, 4014–4017.

"Asymmetric Hydroalkoxylation of Non-Activated Alkenes: Titanium-Catalyzed Cycloisomerization of Allylphenols at High Temperatures"    (International Edition)

 

61. A. Ghose, M. Rebarz, O. V. Maltsev, L. Hintermann, C. Ruckebusch, E. Fron, J. Hofkens, Y. Mély, P. Naumov,* M. Sliwa,* P. Didier,*  J. Phys. Chem. B 2015, 119, 2638–2649

"Emission Properties of Oxyluciferin and Its Derivatives in Water: Revealing the Nature of the Emissive Species in Firefly Bioluminescence"

 

2014

  

60. O. V. Maltsev, R. Rausch, Z.-J. Quan, L. Hintermann,* Eur. J. Org. Chem. 2014, 7426–7432.

"Synthesis of Soai Type 2-Arylpyrimidine-5-carbaldehydes through Desulfurative Cross-Coupling with Arylboronic Acids"

 

59. O. V. Maltsev, L. Yue, M. Rebarz, L. Hintermann, M. Sliwa, C. Ruckebusch, L. Pejov, Y. Liu, P. Naumov,* Chem. Eur. J. 2014, 20, 10782–10790.

"Vibrational Spectra of Chemical and Isotopic Variants of Oxyluciferin, the Light Emitter in the Firefly Bioluminescence"

 

58. O. V. Maltsev, A. Pöthig, L. Hintermann,* Org. Lett. 2014, 16, 1282–1285.

"Synthesis of Soai Aldehydes for Asymmetric Autocatalysis by Desulfurative Cross-Coupling"

 

57. M. W. Jensen, K. Støchkel, C. Kjær, J. L. Knudsen, O. V. Maltsev, L. Hintermann, P. Naumov, B. F. Milne, S. B. Nielsen,* Int. J. Mass Spectrom. 2014, 365/366, 3–9.

"Photoinduced dissociation mass spectroscopy of firefly oxyluciferin anions"

 

56. O. V. Maltsev, N. K. Nath, P. Naumov,* L. Hintermann,* Angew. Chem. 2014, 126, 866–869; Angew. Chem. Int. Ed. 2014, 53, 847–850.

"Why is Firefly Oxyluciferin a Notoriously Labile Substance?"   (International Edition)

 

2013

  

55. O. V. Maltsev, V. Walter, M. J. Brandl, L. Hintermann,* Synthesis 2013, 45, 2763–2767.

"Medium Buffer Effects on the Condensation of L-Cysteine and Aryl Nitriles to (R)-2-Aryl-4,5-dihydrothiazole-4-carboxylic acids" 

 

54. J. Schlüter, M. Blazejak, L. Hintermann,* ChemCatChem 2013, 5, 3309–3315.

"Aluminum Catalyzed Hydroalkoxylation at elevated Temperatures: Fast and Simple Access to Coumarans and other Oxygen Heterocycles"

 

53. M. Rebarz, B.-M. Kukovec, O. V. Maltsev, C. Ruckebusch, L. Hintermann,* P. Naumov,* M. Sliwa,* Chem. Sci. 20134, 3803–3809.

"Deciphering the Protonation and Tautomeric Equilibria of Firefly Oxyluciferin by Molecular Engineering and Multivariate Curve Resolution"

 

52. K. Støchkel, C. N. Hansen, J. Houmøller, L. M. Nielsen, K. Anggara, M. Linares, P. Norman, F. Nogueira, O. V. Maltsev, L. Hintermann, S. B. Nielsen,* P. Naumov,* B. F. Milne,* J. Am. Chem. Soc. 2013, 135, 6485–6493.

"On the Influence of Water on the Electronic Structure of Firefly Oxyluciferin Anions from Absorption Spectroscopy of Bare and Monohydrated Ions in Vacuo“

 

51. H. Wu, L. Hintermann,* Synthesis 201345, 888–892.

"Transfer Hydrogenations of Alkenes with Formate on Pd/C: Synthesis of Dihydrocinchona Alkaloids"   (featured in Synfacts)

 

50. L. Hintermann,* M. Schmitz, O. V. Maltsev, P. Naumov, Synthesis 2013, 45, 308–325.

"Organocatalytic Stereoisomerization versus Alkene-Isomerization: Catalytic Asymmetric Synthesis of 1-Hydroxy-trans-2,5-diphenylphospholane 1-oxide"

 

49. L. Hintermann,* J. Ackerstaff, F. Boeck, Chem. Eur. J. 2013, 19, 2311–2321.

"Inner Workings of a Cinchona-Alkaloid Catalyzed oxa-Michael Cyclization: Evidence for a Concerted Hydrogen-Bond-Network Mechanism” (VIP-Paper)

 

2012

 

48. L. Hintermann,* A. Turočkin, J. Org. Chem. 2012, 77, 11345–11348.

"Reversible Generation of Metastable Enols in the 1,4-Addition of Thioacetic Acid to α-Unsaturated Carbonyl Compounds"

 

47. F. Boeck, M. Blazejak, M. R. Anneser, L. Hintermann,*  Beilstein J. Org. Chem. 2012, 8, 1630–1636.

"Cyclization of ortho-hydroxycinnamates to coumarins under mild conditions: A nucleophilic organocatalysis approach"

 

46. L. Hintermann,* C. Dittmer, Eur. J. Org. Chem. 2012, 5573–5584.

"Asymmetric Ion-Pairing Catalysis of the Reversible Cyclization of 2’-Hydroxychalcone to Flavanone: Asymmetric Catalysis of an Equilibrating Reaction"

 

45. L. Hintermann, Asymmetric Catalysis of Reversible Reactions, in Asymmetric Synthesis - More Methods and Applications, Eds. M. Christmann, S. Bräse, Wiley-VCH, 2012, pp 109–115.

 

44. A. Bertogg, L. Hintermann, D. P. Huber, M. Perseghini, M. Sanna, A. Togni,* Helv. Chim. Acta 2012, 95, 353–403.

"Substrate Range of the Titanium TADDOLate Catalyzed Asymmetric Fluorination of Activated Carbonyl Compounds”

 

43. L. Hintermann, ChemCatChem 2012, 4, 321–322.

"Anti-Markovnikov Hydration of Terminal Alkenes: A Coupled Catalytic Cycle Approach” (Highlight)

 

2011

 

42. T. T. Dang, F. Boeck, L. Hintermann,* J. Org. Chem. 2011, 76, 9353–9361.

"Hidden Brønsted Acid Catalysis: Pathways of Accidental or Deliberate Generation of Triflic Acid from Metal Triflates”

 

41. L. Hintermann, M. Perseghini, A. Togni,* Beilstein J. Org. Chem. 2011, 7, 1421–1435.

"Development of the titanium-TADDOLate-catalyzed asymmetric fluorination of β-ketoesters”   (Open Access)

 

40. F. Boeck, T. Kribber, L. Xiao, L. Hintermann,* J. Am. Chem. Soc. 2011, 133, 8138–8141. 

"Mixed Phosphane η5-CpRuCl(PR3)2 Complexes as Ambifunctional Catalysts for Anti-Markovnikov Hydration of Terminal Alkynes"

 

2010

 

39. L. Hintermann,* M. Schmitz, Y. Chen, Adv. Synth. Catal. 2010352, 2411–2415.

"A Direct Synthesis of Symmetrical (E,E)-1,4-Diaryl-1,3-butadienes by Wenkert Arylation of Thiophene”

 

38. L. Hintermann, Top. Organomet. Chem. 201031, 123–155.

"Recent Developments in Metal-Catalyzed Additions of Oxygen Nucleophiles to Akenes and Alkynes”

 

2009

 

37. L. Hintermann,* T. Kribber, A. Labonne, E. Paciok, Synlett 2009, 2412–2416.

"Aldol Synthesis by anti-Markovnikov Hydration of Propargyloxy Substrates: Feasibility, Stereospecifity, and Reiterative Alkynylation-Hydration"

 

36. L. Hintermann,* L. Xiao, A. Labonne, U. Englert, Organometallics 200928, 5739–5748.

"[CpRu(η6-naphthalene)]PF6 as Precursor in Complex Synthesis and Catalysis with the Cyclopentadienyl-Ruthenium(II) Cation”

 

35. L. Hintermann,* T. T. Dang, A. Labonne, T. Kribber, L. Xiao, P. Naumov, Chem. Eur. J. 200915, 7167–7179.

"The AZARYPHOS Family of Ligands for Ambifunctional Catalysis: Syntheses and Use in Ruthenium-Catalyzed anti-Markovnikov Hydration of Terminal Alkynes

 

34. R. Masuo, K. Ohmori, L. Hintermann, S. Yoshida, K. Suzuki*, Angew. Chem. 2009121, 3514–3517 (Angew. Chem. Int. Ed. 200948, 3462–3465).

"Stereoselective Total Synthesis of FD-594 Aglycon”

 

2008

 

33. L. Hintermann, R. Masuo, K. Suzuki,* Org. Lett. 200810, 4859–4862.

"Solvent-Controllled Leaving-Group Selectivity in Aromatic Nucleophilic Substitution”

 

32. L. Hintermann,* L. Xiao, A. Labonne, Angew. Chem. 2008120, 8370–8374 (Angew. Chem. Int. Ed. 200847, 8246–8250).

"A General and Selective Copper-Catalyzed Cross-Coupling of Tertiary Grignard Reagents with Azacyclic Electrophiles”

 

31. L. Hintermann, K. Suzuki,* Synthesis 2008, 2303–2306.

"2,5-Dihydroxyterephthalates, 2,5-Dichloroquinone-3,6-dicarboxylates, and Polymorphic 2,5-Dichloro-3,6-dihydroxyterephthalates”

 

30. L. Hintermann,* M. Schmitz, Adv. Synth. Cat. 2008350, 1469–1473.

"Enantioselective Synthesis of Phospholenes via Asymmetric Organocatalytic Alkene Isomerization”

 

2007

 

29. L. Hintermann,* J. Org. Chem. 200772, 9790–9793.

"Peak Separation by Adventitious or Added Water in Normal-Phase Chiral HPLC”

 

28. C. Dittmer, G. Raabe, L. Hintermann,* Eur. J. Org. Chem. 2007, 5886–5898.

"Asymmetric Cyclization of 2’-Hydroxychalcones to Flavanones: Catalysis by Chiral Brønsted Acids and Bases”

 

27. L. Hintermann,* Beilstein J. Org. Chem. 20073, 22.

"Expedient Syntheses of the N-Heterocyclic Carbene Precursor Imidazolium Salts IPr·HCl, IMes·HCl and IXy·HCl”      (Open Access)

 

26. T. Kribber, A. Labonne, L. Hintermann,* Synthesis 2007, 2809–2818.

"Iterative Synthesis of Oligo-1,4-Diols via Catalytic anti-Markovnikov Hydration of Terminal Alkynes”

 

25. A. Labonne, L. Zani, L. Hintermann,* C. Bolm,* J. Org. Chem. 2007, 72, 5704–5708.

"Redox-neutral Synthesis of β-Amino Aldehydes from Imines by an Alkynylation/Hydration Sequence”

 

24. L. Hintermann,* M. Schmitz, U. Englert, Angew. Chem. 2007119, 5256–5259 (Angew. Chem. Int. Ed. 200746, 5164–5167).

"Nucleophilic Addition of Organometallic Reagents to Cinchona Alkaloids: Simple Access to Diverse Architectures”

 

23. L. Hintermann,* A. Labonne, Synthesis 2007, 1121–1150.

"Catalytic Hydration of Alkynes and its Application in Synthesis”

 

2006

 

22. A. Labonne, T. Kribber, L. Hintermann,* Org. Lett. 20068, 5853–5856.

"Highly Active in Situ Catalysts for Anti-Markovnikov Hydration of Terminal Alkynes"

 

21. L. Hintermann,* F. Läng, P. Maire, A. Togni, Eur. J. Inorg. Chem. 2006, 1397–1412.

"Interactions of Cationic Palladium(II)- and Platinum(II)-η3-Allyl Complexes with Fluoride: Is Asymmetric Allylic Fluorination a Viable Reaction?"

 

2005

 

20. L. Hintermann, Nachr. Chem. 200553, 1233–1236.

Blickpunkt Synthese: "Eingriffe mit Synthesepinzetten”

 

19. L. Hintermann, Nachr. Chem. 200553, 1030–1033.

Blickpunkt Synthese: "Komplexität als Syntheseziel”

 

18. L. Hintermann, Nachr. Chem. 200553, 776–779.

Blickpunkt Synthese: "Ab-initio-Arensynthese”

 

17. L. Hintermann, Nachr. Chem. 200553, 646–649.

Blickpunkt Synthese: "Die neue Generation der Polyethertoxin-Synthesen”

 

16. L. Hintermann, Nachr. Chem. 200553, 420–423.

Blickpunkt Synthese: "Carbenoide bei Enincyclisierungen”

 

15. L. Hintermann, Nachr. Chem. 200553, 139–143.

Blickpunkt Synthese: "Kohlenstoff ans Steuer”

 

14. L. Hintermann, Wacker Oxidation, in Handbook of C-H Transformations, Ed. G. Dyker, Wiley-VCH, 2005, pp 287-298.

 

2004

 

13. L. Hintermann, Wacker Type Oxidations, in Transition Metals for Organic Synthesis, Eds. M. Beller, C. Bolm, 2nd Ed., Vol. 2, Wiley-VCH, 2004, pp 379–388.

 

12. C. Bolm,* L. Xiao, L. Hintermann, T. Focken, G. Raabe, Organometallics 200423, 2362–2369.

"Synthesis of Chiral Cyrhetrenes and their Application in Asymmetric Catalysis”

 

2003

 

11. R. Frantz, L. Hintermann, M. Perseghini, D. Broggini, A. Togni,* Org. Lett. 20035, 1709–1712.

"Titanium-Catalyzed Stereoselective Geminal Heterodihalogenation of β-Ketoesters”

 

10. L. Hintermann, M. Perseghini, P. Barbaro, A. Togni,* Eur. J. Inorg. Chem. 2003, 601–609.

"Complexes of Rhodium(I) and Iridium(I) with the Chiral Tridentate Phosphane Pigiphos: Structure and Reactivity Studies”

 

2002

 

9. K. Suzuki, L. Hintermann, S. Yamanoi, Cationic Zirconocenes in Organic Synthesis, in Titanium and Zirconium in Organic Synthesis, Ed. I. Marek, Wiley-VCH, 2002, pp 282–318.

 

8. L. Hintermann, D. Broggini, A. Togni,* Helv. Chim. Acta 2002, 85, 1597–1612.

"Titanium Lewis Acids for Asymmetric Catalysis: Synthesis and Structural Characterization of Dichloro[diolato(2–)-κO, κO']bis(solvent)titanium ([TiCl2(diolato)(solvent)2]) Complexes”

 

2001

 

7. A. Togni,* A. Mezzetti,* P. Barthazy, C. Becker, I. Devillers, R. Frantz, L. Hintermann, M. Perseghini, M. Sanna, Chimia 200155, 801–805.

"Developing Catalytic Enantioselective Fluorination”    (Open Access Option)

 

2000

 

6. L. Hintermann, A. Togni,* Angew. Chem. 2000112, 4530–4533 (Angew. Chem. Int. Ed. 200039, 4359–4362).

"Catalytic Enantioselective Fluorination of β-Ketoesters”

 

5. L. Hintermann, A. Togni,* Helv. Chim. Acta 200083, 2425–2435.

"Catalytic Enantioselective Chlorination and Bromination of β-Keto Esters”

 

≤1999

 

4. P. Barthazy, L. Hintermann, R. M. Stoop, M. Wörle, A. Mezzetti,* A. Togni,* Helv. Chim. Acta 199982, 2448–2453.

"Carbon-Fluorine Bond Formation via a Five-Coordinate Fluoro Complex of Ruthenium(II)”

 

3. T. Granier, F. Gaiser, L. Hintermann, A. Vasella,* Helv. Chim. Acta 199780, 1443–1456.

"Synthesis via a Carbohydrate-Derived Münchnone of Pyrrolopyridines (Indolizines) and Imidazopyridines, and Their Evaluation as Inhibitors of β-D-Glucosidases”

 

2. U. Burckhardt, L. Hintermann, A. Schnyder, A. Togni,* Organometallics 199514, 5415–5425.

"Synthesis and Structure of Pyrazole-Containing Ferrocenyl Ligands for Asymmetric Catalysis”

 

1. A. Schnyder, L. Hintermann, A. Togni,* Angew. Chem. 1995107, 996–998 (Angew. Chem. Int. Ed. Engl. 199534, 931–933).

"Strong Electronic Effects on Enantioselectivity in Rhodium-Catalyzed Hydroborations with Novel Pyrazole-Containing Ferrocenyl Ligands”

 

 

Bücher / Books

 

 L. Hintermann, "Katalytische enantioselektive Fluorierung”, Dissertation ETH Nr. 13892, ETH Zürich, Zürich, 2000.    (Original PDF)

 

L. Hintermann, "Sequential Organic Synthesis via Catalytic Heterofunctionalization with Oxygen Nucleophiles”, Habilitationsschrift, RWTH Aachen, Aachen, 2008.

 

 

Patente / Patents

 

L. Hintermann, A. Togni, EP 1151980 A1, 7.11.2001; US 6472345 B2, 29.10. 2002. Assigned to Solvias AG, Basel.

“Catalytic halogenation of activated methylene and methine compounds”