Neue NMR-Methoden

Computerunterstützte Darstellung der experimentellen Bausteine

  • Relaxation-optimized pulse elements (ROPE) (75, 83)
  • Cross-correlated relaxation-optimized transfer (CROP) (82, 92)
  • Transverse relaxation-optimized polarization transfer induced by cross-correlation (TROPIC) (98)
  • Computer-aided design of tailor-made NMR experiments (8, 35, 94)
  • Homonuclear Hartmann-Hahn experiments (HOHAHA) (35)
    ▪ Total correlation spectroscopy (TOCSY) (35, 81)
      ▫ Pulse sequences for J coupled spins:
           ▫ GD sequences (broadband TOCSY) (8)
           ▫ Shaped MLEV (Clean TOCSY) (16)
           ▫ Directed TOCSY (27, 32, 33)
           ▫ SIAM-TOCSY (42)
       ▫ Pulse sequences for dipolar coupled spins:
           ▫ MOCCA sequences (61, 70, 73)
           ▫ Clean TOCSY (87)
     ▪ Tailored correlation spectroscopy (TACSY) (7, 13, 20, 35)
         ▫ Pulse sequences:
            ▫ TT sequences (7, 35)
            ▫ CABBY sequences (HNHA-TACSY, DNA-TACSY) (25)
            ▫ ETA-sequences (E.TACSY) (19, 28)
            ▫ G2-MLEV (PLUSH-TACSY) (34)
            ▫ SIAM-TACSY (42, 73)
            ▫ COIN-TACSY (60)
  • Heteronuclear Hartmann-Hahn experiments (HEHAHA) (35)
       ▪ Broadband HEHAHA
          ▫ Pulse sequences:
            ▫ MGS-Sequences (broadband HEHAHA) (23)
            ▫ JESTER sequences (HIHAHA: heteronuclear isotropic mixing) (35, 67)
            ▫ 180°(MLEV-8) (short cycle time) (52)
        ▪ Bandselective HEHAHA
           ▫ Pulse sequences:
              ▫ G2-MLEV (band-selective HEHAHA) (34)
              ▫ TC sequences (Kin-HEHAHA) (37)
  • Rotating frame nuclear Overhauser effect (ROE) (30)
        ▪ Broadband ROESY with optimal suppression of Hartmann-Hahn transfer
            ▫ Pulse sequence:
            ▫ JS-ROESY (24)
  • Coherence order selective coherence transfer (22, 29, 31, 67, 68, 71)
  • Heteronuclear decoupling
        ▪ Bandselective heteronuclear decoupling in liquids
            ▫ Pulse sequence:
            ▫ G3-MLEV (17)
  • Homonuclear decoupling in solids
        ▪ Broadband decoupling
           ▫ Pulse sequences: (11, 15)
  • Broadband pulses (79, 86, 91, 93)
  • Pattern pulses (97)
  • Shaped pulses for bandselective inversion of dipolar coupled spins (12, 14)