2021   2020

- 2021 -


From Phosphine-Stabilised towards Naked Au8 Clusters through ZIF-8 Encapsulation, K. L. Kollmannsberger, K. Weger, T. Kratky, S. Guenther, O. Tomanec, J. Warnan, R. A. Fischer, Mol. Syst. Des. Eng., DOI: 10.1039/D1ME00107H


Nanometallurgy in solution: organometallic synthesis of intermetallic Pd–Ga colloids and their activity in semi-hydrogenation catalysis, L. Staiger, T. Kratky, S. Günther, A. Urstoeger, M. Schuster, O. Tomanek, R. Zbořil, R. W. Fischer, R. A. Fischer, M. Cokoja, Nanoscale, DOI: 10.1039/D1NR04550D


Metal-organic framework derived multi-functionalized and co-doped TiO2/C nanocomposites for excellent visible-light photocatalysis, M. Z. Hussain, Z. Yang, A. M. E. Khalil, S. Hussain, S. U. Awan, Q. Jia, R. A. Fischer, Y. Zhu, Y. Xia, J. Mater. Sci. Technol., DOI: 10.1016/j.jmst.2021.05.052


Metamorphosis of Heterostructured Surface-Mounted Metal–Organic Frameworks Yielding Record Oxygen Evolution Mass Activities, S. Hou, W. Li, S. Watzele, R. M. Kluge, S. Xue, S. Yin, X. Jiang, M. Döblinger, A. Welle, B. Garlyyev, M. Koch, P. M.-Buschbaum, C. Wöll, A. S. Bandarenka, R. A. Fischer, Adv. Mater., DOI: 10.1002/adma.202103218


A Multifunctional Covalently Linked Graphene-MOF Hybrid as an Effective Chemiresistive Gas Sensor, J. Kolleboyina, M. E. DMello, K. Kesavan, A. Schneemann, M. Otyepka, S. Kment, C. Narayana, S. B. Kalidindi, R. S Varma, R. Zboril, R. A. Fischer, J. Mater. Chem. A 2021, 9, 17434-17441.


Porphyrinic MOF Film for Multifaceted Electrochemical Sensing, Z. Zhou, S. Mukherjee, S. Hou, W. Li, M. Elsner, R. A. Fischer, Angew. Chem. Int. Ed., 2021, 60(37), 20551-20557.


Structural studies of ligand stabilized Ni/Ga clusters by means of vibrational spectroscopy and theoretical calculations, J. Mink, L. Staiger, M. Muhr, C. Gemel, M. Drees, L. Hajba, J. Mihály, C. Németh, B. V. Lokshin, K. Hemmer, M. Schütz, M. Cokoja, R. A. Fischer, J. Raman Spectrosc., DOI: 10.1002/jrs.6199.


Enabling LIFDI-MS measurements of highly air sensitive organometallic compounds: a combined MS/glovebox technique, M. Muhr, P. Heiß, M. Schütz, R. Bühler, C. Gemel, M. H. Linden, H. B. Linden, R. A. Fischer, Dalton Trans. 202150(26), 9031–9036.


Intermetallic phases meet intermetalloid clusters, M. Schütz, C. Gemel, W. Klein, R. A. Fischer, T. F. Fässler, Chem. Soc. Rev. 2021, 50, 8496-8510.


Host-Guest Interactions in Metal-Organic Framework Isoreticular Series for Molecular Photocatalytic CO2 Reduction, P. M. Stanley, J. Haimerl, C. Thomas, A. Urstoeger, M. Schuster, N. B. Shustova, A. Casini, B. Rieger, J. Warnan, R. A. Fischer, Angew. Chem. Int. Ed. 2021, 60(33), 17854-17860.


Understanding entrapped molecular photosystem and metal-organic framework synergy for improved solar fuel production, P. M. Stanley, M. Parkulab, B. Rieger, J. Warnan, R. A. Fischer, Faraday Discuss., DOI: 10.1039/D1FD00009H.


Surface-Mounted Metal–Organic Frameworks: Past, Present, and Future Perspectives, A. L. Semrau, Z. Zhou, S. Mukherjee, M. Tu, W. Li, R. A. Fischer, Langmuir 202137(23), 6847–6863.


Two-Coordinate, Nonlinear Vanadium(II) and Chromium(II) Complexes of the Silylamide Ligand–N(SiMePh2)2: Characterization and Confirmation of Orbitally Quenched Magnetic Moments in Complexes with Sub-d5 Electron Configurations, K. Freitag, C. R. Stennett, A. MansikkamäkiR. A. Fischer, P. P. Power, Inorg. Chem. 2021, 60(6), 4108-4115.


Exploring Cu/Al cluster growth and reactivity: From embryonic building blocks to intermetalloid, open-shell superatoms, M. Schütz, C. Gemel, M. Muhr, C. Jandl, S. Kahlal, J.-Y. Saillard, R. A. Fischer, Chem. Sci. 2021, 12(19), 6588–6599.


Scrutinizing ligand exchange reactions in the formation of the precious group metal-organic framework RuII,II-HKUST-1: The impact of diruthenium tetracarboxylate precursor and coordination modulator choice, W. R. Heinz, D. Staude, D. Mayer, H. Bunzen, R. A. Fischer, Dalton Trans. 2021, 50(15), 5226–5235.


Homochiral metal–organic frameworks for enantioseparation, J. Liu, S. Mukherjee, F. Wang, R. A. Fischer, J. Zhang, Chem. Soc. Rev. 2021, 50(9), 5706–5745.


Charge-Transfer-Induced Electrical Conductivity in a Tetrathiafulvalene-Based Metal–Organic Framework, D. Ukaj, H. Bunzen, J. Berger, G. Kieslich, R. A. Fischer, Chem. Mater. 2021, 33(7), 2532–2542.


Enhanced Hydrogenation Catalytic Activity of Ruthenium Nanoparticles by Solid‐Solution alloying with Molybdenum, S. Okazoe, L. Staiger, M. Cokoja, K. Kusada, T. Yamamoto, T. Toriyama, S. Matsumura, H. Kitagawa, R. A. Fischer, Eur. J. Inorg. Chem. 2021(12), 1186–1189.


High‐Quality Thin Films of UiO‐66‐NH2 by Coordination Modulated Layer‐by‐Layer Liquid Phase Epitaxy, A. L. Semrau, R. A. Fischer, Chem. Eur. J. 202127(33), 8509–8516.


Molecular Oxygen Activation by Redox-Switchable Anthraquinone-Based Metal–Organic Frameworks, J. G. M. de Carvalho, R. A. Fischer, A. Pöthig, Inorg. Chem. 202160(7), 4676–4682.


An in situ investigation of the thermal decomposition of metal-organic framework NH2-MIL-125 (Ti), M. Z. Hussain, M. Bahri, W. R. Heinz, Q. Jia, O. Ersen, T. Kratky, R. A.Fischer, Y. Zhu, Y. Xia, Microporous Mesoporous Mater. 2021316, 110957.


Tuning the Properties of MOF‐808 via Defect Engineering and Metal Nanoparticle Encapsulation, R. Hardian, S. Dissegna, A. Ullrich, P. L. Llewellyn, M.-V. Coulet, R. A. Fischer, Chem. Eur. J. 202127(22), 6804–6814.


Bimetal-organic framework derived multi-heterostructured TiO2/CuxO/C nanocomposites with superior photocatalytic H2 generation performance, M. Z. Hussain, B. van der Linden, Z. Yang, Q. Jia, H. Chang, R. A. Fischer, F. Kapteijn, Y. Zhu, Y. Xia, J. Mater. Chem. A 20219(7), 4103–4116.


Open Framework Material Based Thin Films: Electrochemical Catalysis and State‐of‐the‐art Technologies, W. Li, S. Mukerjee, B. Ren, R. Cao, R. A. Fischer, Adv. Energy Mater., DOI: 10.1002/aenm.202003499.


Defect-Engineered Metal–Organic Frameworks: A Thorough Characterization of Active Sites Using CO as a Probe Molecule, J. Wang, W. Wang, Z. Fan, S. Chen, A. Nefedov, S. Heißler, R. A. Fischer, C. Wöll, Y. Wang, J. Phys. Chem. C 2021125(1), 593–601.


Entrapped Molecular Photocatalyst and Photosensitizer in Metal–Organic Framework Nanoreactors for Enhanced Solar CO2 Reduction, P. M. Stanley, C. Thomas, E. Thyrhaug, A. Urstoeger, M. Schuster, J. Hauer, B. Rieger, J. Warnan, R. A. Fischer, ACS Catal. 202111(2), 871–882.


An Investigation into the Intrinsic Peroxidase‐Like Activity of Fe‐MOFs and Fe‐MOFs/Polymer Composites, B. Thakur, V. V. Karve, D. T. Sun, A. L. Semrau, L. J. K. Weiß, L. Grob, R. A. Fischer, W. L. Queen, B. Wolfrum, Adv. Mater. Technol. 2021, 6(5), 2001048.


In Situ Tracking of Wetting‐Front Transient Heat Release on a Surface‐Mounted Metal–Organic Framework, W. Li, G. Yang, A. Terzis, S. Mukherjee, C. He, J. Wu, B. Weigand, R. A. Fischer, Adv. Mater. 2021, 33(14), 2006980.


Defect engineering: an effective tool for enhancing the catalytic performance of copper-MOFs for the click reaction and the A3 coupling, Z. Fan, Z. Wang, M. Cokoja, R. A. Fischer, Catal. Sci. Technol. 202111(7), 2396–2402.


Exploitation of Intrinsic Confinement Effects of MOFs in Catalysis, K. Hemmer, M. Cokoja, R. A. Fischer, ChemCatChem 2021, 13(7), 1683–1691.


A Nitrophenyl-Carbazole based Push-Pull Linker as a Building Block for Non-Linear Optical Active Coordination Polymers: A Structural and Photophysical Study, S. J. Weishäupl, D. C. Mayer, E. Thryhaug, J. Hauer, A. Pöthig, R. A. Fischer, Dyes Pigm. 2021186, 109012.


Configurational Entropy Driven High-Pressure Behaviour of a Flexible Metal-Organic Framework (MOF), P. Vervoorts, J. Keupp, A. Schneemann, C. L. Hobday, D. Daisenberger, R. A. Fischer, R. Schmid, G. Kieslich, Angew. Chem. Int. Ed. 202160(2), 787–793.


Steric and Electronic Effects of Phosphane Additives on the Catalytic Performance of Colloidal Palladium Nanoparticles in the Semi‐Hydrogenation of Alkynes, L. Staiger, T. Kratky, S. Günther, O. Tomanek, R. Zbořil, R. W. Fischer, R. A. Fischer, M. Cokoja, ChemCatChem 202113(1), 227–234.


Covalent Graphene‐MOF Hybrids for High‐Performance Asymmetric Supercapacitors, K. Jayaramulu, M. Horn, A. Schneemann, H. Saini, A. Bakandritsos, V. Ranc, M. Petr, V. Stavila, C. Narayana, B. Scheibe, S. Kment, M. Otyepka, N. Motta, D. Dubal, R. Zbořil, R. A. Fischer, Adv. Mater. 202133(4), 2004560.


Surface functionalized N-C-TiO2/C nanocomposites derived from metal-organic framework in water vapour for enhanced photocatalytic H2 generation, M. Z. Hussain, Z. Yang, B. van der Linden, Z. Huang, Q. Jia, E. Cerrato, R. A. Fischer, F. Kapteijn, Y. Zhu, Y. Xia, J. Energy Chem. 202157, 485–495.


Direct X-ray and electron-beam lithography of halogenated zeolitic imidazolate frameworks, M. Tu, B. Xia, D. E. Kravchenko, M. L. Tietze, A. J. Cruz, I. Stassen, T. Hauffman, J. Teyssandier, S. de Feyter, Z. Wang, R. A. Fischer, B. Marmiroli, H. Amenitsch, A. Torvisco, M. de J. Velásquez-Hernández, P. Falcaro, R. Ameloot, Nat. Mater. 202120(1), 93–99.

- 2020 -


Thermal defect engineering of precious group metal–organic frameworks: impact on the catalytic cyclopropanation reaction, W. R. Heinz, R. Junk, I. Agirrezabal-Telleria, B. Bueken, H. Bunzen, T. Gölz, M. Cokoja, D. De Vos, R. A. Fischer, Catal. Sci. Technol. 202010(23), 8077–8085.


Metal Halide Perovskite@Metal‐Organic Framework Hybrids: Synthesis, Design, Properties, and Applications, S. K. Yadav, G. K. Grandhi, D. P. Dubal, J. C. de Mello, M. Otyepka, R. Zboril, R. A. Fischer, K. Jayaramulu, Small 202016(47), 2004891.


Dual-Function HKUST-1: Templating and Catalyzing Formation of Graphitic Carbon Nitride Quantum Dots Under Mild Conditions, M. K. Albolkany, Y. Wang, W. Li, S. Arooj, C.-H. Chen, N. Wu, Y. Wang, R. Zbořil, R. A. Fischer, B. Liu, Angew. Chem. Int. Ed. 2020, 59(48), 21499–21504.


Selective Positioning of Nanosized Metal–Organic Framework Particles at Patterned Substrate Surfaces, A. L. Semrau, S. P. Pujari, P. M. Stanley, S. Wannapaiboon, B. Albada, H. Zuilhof, R. A. Fischer, Chem. Mater. 2020, 32(23), 9954–9963.


Porphyrin based metal-organic framework films: nucleation and growth, Z. Zhou, S. Mukherjee, J. Warnan, W. Li, S. Wannapaiboon, S. Hou, K. Rodewald, B. Rieger, P. G. Weidler, C. Wöll, R. A. Fischer, J. Mater. Chem. A 2020, 8(48), 25941–25950.


Thermal Defect Engineering of Precious Group Metal−Organic Frameworks: A Case Study on Ru/Rh-HKUST‐1 Analogues, W. R. Heinz, I. Agirrezabal-Telleria, R. Junk, J. Berger, J. Wang, D. I. Sharapa, M. Gil-Calvo, I. Luz, M. Soukri, F. Studt, Y. Wang, C. Wöll, H. Bunzen, M. Drees, R. A. Fischer, ACS Appl. Mater. Interfaces 202012(36), 40635–40647.


Defect Engineering of Copper Paddlewheel-Based Metal−Organic Frameworks of Type NOTT-100: Implementing Truncated Linkers and Its Effect on Catalytic Properties, Z. Fan, J. Wang, W. Wang, S. Burger, Z. Wang, Y. Wang, C. Wöll, M. Cokoja, R. A. Fischer, ACS Appl. Mater. Interfaces 202012(34), 27993–38002.


Postsynthetic Framework Contraction Enhances the Two-Photon Absorption Properties of Pillar-Layered Metal−Organic Frameworks, D. C. Mayer, J. K. Zarȩba, G. Raudaschl-Sieber, A. Pöthig, M. Chołuj, R. Zaleśny, M. Samoć, R. A. Fischer, Chem. Mater. 202032(13), 5682–5690.


Hierarchical Porous Graphene–Iron Carbide Hybrid Derived From Functionalized Graphene-Based Metal–Organic Gel as Efficient Electrochemical Dopamine Sensor, E. C. Vermisoglou, P. Jakubec, O. Malina, V. Kupka, A. Schneemann, R. A. Fischer, R. Zbořil, K. Jayaramulu, M. Otyepka, Front. Chem. 20208, 544.


Contrasting Structure and Bonding of a Copper-Rich and a Zinc-Rich Intermetalloid Cu/Zn Cluster, M. Schütz, M. Muhr, K. Freitag, C. Gemel, S. Kahlal, J.-Y. Saillard, A. C. H. Da Silva, J. L. F. Da Silva, T. F. Fässler, R. A. Fischer, Inorg. Chem. 202059(13), 9077–9085.


Inter-conversion between zeolitic imidazolate frameworks: a dissolution–recrystallization process, M. Tu, S. Wannapaiboon, R. A. Fischer, J. Mater. Chem. A 20208(27), 13710–13717.


Synthesis of plasmonic Fe/Al nanoparticles in ionic liquids, A. Schmitz, H. Meyer, M. Meischein, A. Garzon Manjon, L. Schmolke, B. Giesen, C. Schlusener, P. Simon, Y. Grin, R. A. Fischer, C. Scheu, A. Ludwig, C. Janiak, RSC Adv. 202010(22), 12891–12899.


Formation of a Propeller-Shaped Ni4Ga3 Cluster Supported by Transmetalation of Cp* from Ga to Ni, M. Muhr, J. Hornung, J. Weßing, C. Jandl, C. Gemel, R. A. Fischer, Inorg. Chem. 202059(7), 5086–5092.


Substantial Turnover Frequency Enhancement of MOF Catalysts by Crystallite Downsizing Combined with Surface Anchoring, A. L. Semrau, P. M. Stanley, A. Urstoeger, M. Schuster, M. Cokoja, R. A. Fischer, ACS Catal. 202010(5), 3203 – 3211.


Advanced Bifunctional Oxygen Reduction and Evolution Electrocatalyst Derived from Surface-Mounted Metal–Organic Frameworks, W. Li, S. Xue, S. Watzele, S. Hou, J. Fichtner, A. L. Semrau, L. Zhou, A. Welle, A. S. Bandarenka, R. A. Fischer, Angew. Chem. Int. Ed. 202059(14), 5837–5843.


Coordinated Water as New Binding Sites for the Separation of Light Hydrocarbons in Metal−Organic Frameworks with Open Metal Sites, P. Vervoorts, A. Schneemann, I. Hante, J. Pirillo, Y. Hijikata, T. Toyao, K. Kon, K.-i. Shimizu, T. Nakamura, S.-i. Noro, R. A. Fischer, ACS Appl. Mater. Interfaces 202012(8), 9448–9456.


Defect‐Engineered Ruthenium MOFs as Versatile Heterogeneous Hydrogenation Catalysts, K. Epp, I. Luz, W. R. Heinz, A. Rapeyko, F. X. Llabrés i Xamena, R. A. Fischer, ChemCatChem 202012(6), 1720–1725.


Defect Creation in Surface-Mounted Metal−Organic Framework Thin Films, Z. Wang, S. Henke, M. Paulus, A. Welle, Z. Fan, K. Rodewald, B. Rieger, R. A. Fischer, ACS Appl. Mater. Interfaces 2020, 12(2), 2655–2661.


Combined Experimental and Theoretical Study on Hampered Phosphine Dissociation in Heteroleptic Ni/Zn Complexes, P. Heiß, J. Hornung, X. Zhou, C. Jandl, A. Pöthig, C. Gemel, R. A. Fischer, Inorg. Chem. 202059(1), 514–522.


The synergistic effect of heterostructured dissimilar metal–organic framework thin films on adsorption properties, Z. Wang, S. Wannapaiboon, S. Henke, M. Paulus, K. Rodewald, B. Rieger, R. A. Fischer, J. Mater. Chem A 20208(26), 12990–12995.


Scrutinizing the Pore Chemistry and the Importance of Cu(I) Defects in TCNQ-Loaded Cu3(BTC)2 by a Multitechnique Spectroscopic Approach, C. Schneider, M. Mendt, A. Pöppl, V. Crocellà, R. A. Fischer, ACS Appl. Mater. Interfaces 202012(1), 1024–1035.